Buonocore MG. A simple method of increasing the adhesion of acrylic filling materials to enamel surfaces.. J Dent Res. 1955; 34:849-853
Nordenvall KJ, Brannstrom M, Malmgren O. Etching of deciduous teeth and young and old permanent teeth. A comparison between 15 and 60 seconds of etching.. Am J Orthod. 1980; 78:99-108
Barkmeier WW, Shaffer SE, Gwinnett AJ. Effects of 15 vs 60 second enamel acid conditioning on adhesion and morphology.. Oper Dent. 1986; 11:111-116
Johnston CD, Burden DJ, Hussey DL, Mitchell CA. Bonding to molars – the effect of etch time (an in vitro study).. Eur J Orthod. 1998; 20:195-199
Kimmes NS, Barkmeier WW, Erickson RL, Latta MA. Adhesive bond strengths to enamel and dentin using recommended and extended treatment times.. Oper Dent. 2010; 35:112-119
Fleming PS, Johal A, Pandis N. Self-etch primers and conventional acid-etch technique for orthodontic bonding: a systematic review and meta-analysis.. Am J Orthod Dentofacial Orthop. 2012; 142:83-94
Hu H, Li C, Li F, Chen J, Sun J, Zou S Enamel etching for bonding fixed orthodontic braces.. Cochrane Database Syst Rev. 2013;
Hallgren A, Oliveby A, Twetman S. L(+)-lactic acid production in plaque from orthodontic appliances retained with glass ionomer cement.. Br J Orthod. 1994; 21:23-26
Hotz P, McLean JW, Sced I, Wilson AD. The bonding of glass ionomer cements to metal and tooth substrates.. Br Dent J. 1977; 142:41-47
Millett DT, McCabe JF. Orthodontic bonding with glass ionomer cement – a review.. Eur J Orthod. 1996; 18:385-399
Benson PE, Shah AA, Millett DT, Dyer F, Parkin N, Vine RS. Fluorides, orthodontics and demineralization: a systematic review.. J Orthod. 2005; 32:102-114
Venezie RD, Vadiakas G, Christensen JR, Wright JT. Enamel pretreatment with sodium hypochlorite to enhance bonding in hypocalcified amelogenesis imperfecta: case report and SEM analysis.. Pediatr Dent. 1994; 16:433-436
Arkutu N, Gadhia K, McDonald S, Malik K, Currie L. Amelogenesis imperfecta: the orthodontic perspective.. Br Dent J. 2012; 212:485-489
Hosein I, Sherriff M, Ireland AJ. Enamel loss during bonding, debonding, and cleanup with use of a self-etching primer.. Am J Orthod Dentofacial Orthop. 2004; 126:717-724
Zope A, Zope-Khalekar Y, Chitko SS, Kerudi VV, Patil HA, Bonde PV Comparison of self-etch primers with conventional acid etching system on orthodontic brackets.. J Clin Diagn Res. 2016; 10:ZC19-ZC22
Ng'ang'a PM, Ogaard B, Cruz R, Chindia ML, Aasrum E. Tensile strength of orthodontic brackets bonded directly to fluorotic and nonfluorotic teeth: an in vitro comparative study.. Am J Orthod Dentofacial Orthop. 1992; 102:244-250
Isci D, Sahin Saglam AM, Alkis H, Elekdag-Turk S, Turk T. Effects of fluorosis on the shear bond strength of orthodontic brackets bonded with a self-etching primer.. Eur J Orthod. 2011; 33:161-166
Ribeiro AA, de Morais AV, Brunetto DP, Ruellas AC, de Araujo MT. Comparison of shear bond strength of orthodontics brackets on composite resin restorations with different surface treatments.. Dental Press J Orthod. 2013; 18:98-103
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Bonding brackets with composite resin is considered the gold standard in orthodontics. However, this can be challenging, especially where there is a requirement to bond to surfaces other than enamel, or where the enamel is defective. A choice of bonding modalities exists for these situations, and it is important that clinicians keep up-to-date with current techniques and practice. An overview of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic) is presented. Furthermore, a summary table providing a step-by-step guide for bonding techniques to various surfaces is provided.
CPD/Clinical Relevance: We provide an overview of the evidence and techniques available to the orthodontist for bonding brackets to enamel and other surfaces including: composite, porcelain, gold, amalgam and acrylic.
Article
Advancements in restorative dentistry over the last 50 years have meant that teeth previously considered of hopeless prognosis can now be restored and maintained. Despite the obvious advantages of tooth maintenance, this poses several challenges for the orthodontist, including the various surfaces to which brackets may need to be attached. This necessitates modifications to conventional bonding techniques.
This article provides an overview of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic). Furthermore, a summary table providing a step-by-step guide on bonding techniques for the various surfaces discussed is provided as an aide memoire.
Enamel
Direct bonding to enamel utilizes three principal agents: an enamel surface conditioner, a primer solution and an adhesive resin.
Surface conditioner
This creates micro-porosity and a high-energy enamel surface. Scanning electron micrographs are presented of normal enamel (Figure 1) and enamel that has been etched with 37% phosphoric acid for 15 seconds (Figure 2).
Primer
This flows into the etched surface to create resin tags so that, subsequently, a mechanical bond is created between the adhesive resin and the tooth surface.
Adhesive resin
This is the ‘cement’ which permits the bonding of materials to the tooth surface.
Buonocore originally introduced the enamel acid etch technique in 1955; he proposed conditioning with 85% phosphoric acid for 30 seconds.1 However, as research and practice evolved, it was found that 37% phosphoric acid utilized for 15 seconds was sufficient to develop a strong, durable bond to anterior teeth.2,3 For molars it has been suggested that an etching time of at least 30 seconds be utilized when bonding to the buccal surfaces of first molars, as it produces a more consistent bond strength compared to etching for 15 seconds.4
Self-etching primers (SEPs) provide a one stage alternative to conventional etching followed by primer application. Advantages of this approach include: ease of use, decreased technique sensitivity and a reduction in chairside time.5
The evidence comparing the relative benefits of SEPs and the acid etch technique is equivocal. A systematic review by Fleming et al concluded that there was weak evidence demonstrating higher odds of failure with SEPs over a 12-month period, but strong evidence for a time saving of approximately 8 minutes for full arch bonding.6 However, a more recent review concluded that there was no useable evidence to enable conclusions about failure rates for SEPs in comparison to acid etch and which is the most appropriate concentration or etching time.7
Although this present article focuses on the use of composite resin for bonding, it should be noted that glass ionomer cement (GIC) is an alternative adhesive. Glass ionomer cements can release fluoride and thus may prevent enamel decalcification8 whilst adhering to both enamel and metal.9 The bond strength is, however, weaker than composite resin and they have higher failure rates.10 There is some evidence that use of a GIC for bonding brackets may reduce the occurrence and severity of white spot lesions during orthodontic treatment,11 however, further high quality research is required.
In the absence of strong evidence in favour of either system, the choice of bonding modality remains at the discretion of the operator.
Bonding to defective enamel
It is not uncommon to encounter enamel surfaces that have developmental defects, such as those in amelogenesis imperfecta and molar incisor hypomineralization. Figures 3, 4 and 5 highlight the poor enamel formation in amelogenesis imperfecta, whilst Figures 6, 7 and 8 present a mild case of molar incisor hypomineralization. Clinical experience has shown that bond failure rates are higher in these cases; one reason for this may include the increased protein content of affected enamel. To address this, Venezie et al described the use of sodium hypochlorite to remove excess protein and improve the quality of etch in amelogenesis imperfecta cases.12 The evidence for improved bracket retention with these methods, however, remains weak and would not routinely be recommended.13 Whilst conventional etching is discouraged in these cases, as phosphoric acid may result in more enamel loss, SEPs may be used as an alternative because they produce a milder etch pattern and remove less enamel.14,15 Furthermore, the use of SEPs may help to reduce sensitivity that may be experienced by the patient during etching, rinsing and air-drying. Alternatively, the banding of molars may also be preferable.13
Bonding to composite labial veneers may result in increased bracket retention in cases affected by severe defects of enamel, as it is proposed that bonding to a larger area of composite resin increases bond strength when compared to bonding to the defective enamel alone.
Bonding to fluorosed enamel
For bonding to mildly fluorosed teeth, it has been reported that there is no significant difference in sheer bond strengths compared to that of normal enamel.16 An in vitro study by Isci et al, however, found that SEPs showed lower shear bond strength values for orthodontic brackets bonded to mildly fluorosed enamel.17
Composite resin
Bonding to composite resin requires superficial roughening, either through sandblasting with aluminium oxide or with diamond burs.18 Furthermore, an in vitro study concluded that a clinically acceptable bond strength can be achieved by surface conditioning of aged resin composite via the application of hydrofluoric acid, sandblasting with aluminium oxide, sodium bicarbonate particle abrasion, or a diamond bur.19 Subsequent bonding of brackets can be achieved by traditional orthodontic composites.
Porcelain
Bonding orthodontic brackets to porcelain/ceramic surfaces has a greater failure rate compared to enamel bonding.20 Therefore, several techniques have been suggested, which include:
Application of silane porcelain primer and lightly air-dry;
Application of adhesive resin bonding agent.
Hydrofluoric acid is highly corrosive, and should be used under rubber dam isolation and with high volume suction to prevent injury to the patient. Several primers are available for bonding to Zirconium crowns, for example, Assure®Plus (Reliance Orthodontic Products), All-Bond Universal® (Bisco, Schaumburg, Ill) and Scotchbond™ Universal (3M Unitek).23
Gold
Conventional acid etching is ineffective in the preparation of gold surfaces for mechanical retention of orthodontic attachments. Büyükyilmaz et al suggested that intra-oral sandblasting is utilized.24 This can be followed by bonding with a methacryloyloxyethyl trimellitate anhydride, (4-META) metal-bonding adhesive resin. Subsequent bonding of brackets can be achieved by traditional orthodontic composites. Research has shown that the bond strength achieved is comparable to that of acid-etched enamel.24
Amalgam
Successful bonding of orthodontic attachments to an amalgam surface requires conditioning of the amalgam (for example sandblasting), and use of a 4-META resin. Subsequent bonding of brackets to sandblasted and alloy primer-coated amalgam surfaces can be achieved by traditional primers and orthodontic composites.25
An alternative is to use a hydrophilic primer containing biphenyl dimethacrylate, such as Assure® (Reliance Orthodontic Products). This allows for composite bonding to amalgam following sandblasting without the use of a separate metal primer.23 Subsequent bonding of brackets can be achieved by traditional orthodontic composites.
Acrylic
Acrylic teeth are often incorporated into orthodontic appliances as prosthetic teeth to mask spaces. Orthodontic brackets can be bonded to acrylic teeth using mechanical and chemical methods, or a combination of both. Mechanical retention includes sandblasting with aluminium oxide particles,26 the creation of undercut holes to facilitate a micro-mechanical ‘lock’ or roughening the surface with diamond or tungsten carbide burs.27 Chemical retention can be achieved using adhesive materials, such as cyanoacrylate.28
Discussion
Advancements in dentistry over the last 50 years have meant that teeth previously considered of hopeless prognosis can now be restored and maintained. Orthodontic clinicians must therefore possess the knowledge and skills to modify conventional bonding techniques, which are summarized in Table 1. A summary table (Table 2) has been developed as an aide memoire for required alterations to the enamel bonding process that allow for orthodontic brackets to be bonded to composite, porcelain, zirconia, metal and acrylic.
Etch and Rinse
SEP
Thorough prophylaxis − Rinse & Dry
Isolate the teeth for etching. With a microbrush, dab the etching agent (phosphoric acid) onto area to be bonded
Allow 15−30 seconds for etching
Rinse & Dry for 10 seconds
The etched area should appear frosty white. If not, re-etch for an additional 20 seconds
Apply 1 coat of hydrophilic primer resin and lightly dry with air
Proceed with the application of adhesive resin and bracket
Light cure 10−20 seconds
Thorough prophylaxis − Rinse & Dry
Using a microbrush, apply a small amount of mixed solution to the enamel and scrub for 5 seconds where the bracket will be applied
Dry the enamel surface with 2 bursts of compressed air
Proceed with the application of adhesive resin and bracket
Light cure 10−20 seconds
Bonding to a Composite Surface
Bonding to a Porcelain Surface
Bonding to a Zirconia Surface
Bonding to a Metal Surface (Gold, Amalgam, Stainless Steel)
Bonding to an Acrylic Surface
Thorough prophylaxis − Rinse & Dry
Roughen the composite surface with a fine diamond bur − Rinse & Dry
If there is enamel present – Etch, Rinse & Dry
Apply 1 coat of hydrophilic primer resin and lightly dry with air
Proceed with the application of adhesive resin and bracket
Light cure for double time
Thorough prophylaxis − Rinse & Dry
Sandblast porcelain surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry
OR
Isolate tooth, etch with 9.6% hydrofluoric acid for 1 minute, Rinse 30 seconds & Dry
Apply 1 thin layer of silane coupling agent − lightly dry with air
Apply 1 coat of hydrophilic primer resin & air dry
Proceed with application of adhesive resin and bracket
Light cure for double time
Sandblast metal surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry
OR
Isolate tooth, etch with 9.6% hydrofluoric acid for 1 minute, Rinse 30 seconds & Dry
Apply 1 thin layer of silane coupling agent − lightly dry with air
Apply 1 coat of hydrophilic primer resin & air dry
Light cure resin for 10 seconds
Proceed with application of adhesive resin and bracket
Light cure for double time
Thorough prophylaxis − Rinse & Dry
Sandblast metal surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry. If no enamel present proceed to Step 4.
If there is enamel present – Etch, Rinse & Dry
Apply 1 coat of hydrophilic primer resin & air dry
Proceed with application of adhesive resin and bracket
Light cure for double time
Roughen the acrylic surface with a fine diamond bur − Rinse & Dry
Apply one coat of hydrophilic primer resin and lightly dry with air
Proceed with the application of adhesive resin and bracket
Light cure for double time
This article has provided an overview of some of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic). Despite all efforts to improve bond strength in compromising situations, repeated bond failures may still occur. In these situations, it may be necessary to resort to banding teeth and accepting the associated disadvantages.
Conclusion
There is weak evidence indicating a higher odds of failure with SEPs than etch and rinse over 12 months in orthodontic patients;
In the absence of clear evidence to favour either system, the choice of bonding modality remains at the discretion of each operator;
A convenient table is presented to act as an aide memoire for readers highlighting techniques for bonding to enamel and the various restorative materials encountered in adolescent and adult orthodontic patients.