References

Buonocore MG. A simple method of increasing the adhesion of acrylic filling materials to enamel surfaces.. J Dent Res. 1955; 34:849-853
Nordenvall KJ, Brannstrom M, Malmgren O. Etching of deciduous teeth and young and old permanent teeth. A comparison between 15 and 60 seconds of etching.. Am J Orthod. 1980; 78:99-108
Barkmeier WW, Shaffer SE, Gwinnett AJ. Effects of 15 vs 60 second enamel acid conditioning on adhesion and morphology.. Oper Dent. 1986; 11:111-116
Johnston CD, Burden DJ, Hussey DL, Mitchell CA. Bonding to molars – the effect of etch time (an in vitro study).. Eur J Orthod. 1998; 20:195-199
Kimmes NS, Barkmeier WW, Erickson RL, Latta MA. Adhesive bond strengths to enamel and dentin using recommended and extended treatment times.. Oper Dent. 2010; 35:112-119
Fleming PS, Johal A, Pandis N. Self-etch primers and conventional acid-etch technique for orthodontic bonding: a systematic review and meta-analysis.. Am J Orthod Dentofacial Orthop. 2012; 142:83-94
Hu H, Li C, Li F, Chen J, Sun J, Zou S Enamel etching for bonding fixed orthodontic braces.. Cochrane Database Syst Rev. 2013;
Hallgren A, Oliveby A, Twetman S. L(+)-lactic acid production in plaque from orthodontic appliances retained with glass ionomer cement.. Br J Orthod. 1994; 21:23-26
Hotz P, McLean JW, Sced I, Wilson AD. The bonding of glass ionomer cements to metal and tooth substrates.. Br Dent J. 1977; 142:41-47
Millett DT, McCabe JF. Orthodontic bonding with glass ionomer cement – a review.. Eur J Orthod. 1996; 18:385-399
Benson PE, Shah AA, Millett DT, Dyer F, Parkin N, Vine RS. Fluorides, orthodontics and demineralization: a systematic review.. J Orthod. 2005; 32:102-114
Venezie RD, Vadiakas G, Christensen JR, Wright JT. Enamel pretreatment with sodium hypochlorite to enhance bonding in hypocalcified amelogenesis imperfecta: case report and SEM analysis.. Pediatr Dent. 1994; 16:433-436
Arkutu N, Gadhia K, McDonald S, Malik K, Currie L. Amelogenesis imperfecta: the orthodontic perspective.. Br Dent J. 2012; 212:485-489
Hosein I, Sherriff M, Ireland AJ. Enamel loss during bonding, debonding, and cleanup with use of a self-etching primer.. Am J Orthod Dentofacial Orthop. 2004; 126:717-724
Zope A, Zope-Khalekar Y, Chitko SS, Kerudi VV, Patil HA, Bonde PV Comparison of self-etch primers with conventional acid etching system on orthodontic brackets.. J Clin Diagn Res. 2016; 10:ZC19-ZC22
Ng'ang'a PM, Ogaard B, Cruz R, Chindia ML, Aasrum E. Tensile strength of orthodontic brackets bonded directly to fluorotic and nonfluorotic teeth: an in vitro comparative study.. Am J Orthod Dentofacial Orthop. 1992; 102:244-250
Isci D, Sahin Saglam AM, Alkis H, Elekdag-Turk S, Turk T. Effects of fluorosis on the shear bond strength of orthodontic brackets bonded with a self-etching primer.. Eur J Orthod. 2011; 33:161-166
Ribeiro AA, de Morais AV, Brunetto DP, Ruellas AC, de Araujo MT. Comparison of shear bond strength of orthodontics brackets on composite resin restorations with different surface treatments.. Dental Press J Orthod. 2013; 18:98-103
Bayram M, Yesilyurt C, Kusgoz A, Ulker M, Nur M. Shear bond strength of orthodontic brackets to aged resin composite surfaces: effect of surface conditioning.. Eur J Orthod. 2011; 33:174-179
Grewal Bach GK, Torrealba Y, Lagravere MO. Orthodontic bonding to porcelain: a systematic review.. Angle Orthod. 2014; 84:555-560
Zachrisson BU, Büyükyilmaz T. Recent advances in bonding to gold, amalgam, and porcelain.. J Clin Orthod. 1993; 27:661-675
Bourke BM, Rock WP. Factors affecting the shear bond strength of orthodontic brackets to porcelain.. Br J Orthod. 1999; 26:285-290
Gange P. The evolution of bonding in orthodontics.. Am J Orthod Dentofacial Orthop. 2015; 147:S56-63
Büyükyilmaz T, Zachrisson YO, Zachrisson BU. Improving orthodontic bonding to gold alloy.. Am J Orthod Dentofacial Orthop. 1995; 108:510-518
Büyükyilmaz T, Zachrisson BU. Improved orthodontic bonding to silver amalgam. Part 2. Lathe-cut, admixed, and spherical amalgams with different intermediate resins.. Angle Orthod. 1998; 68:337-344
Blakey R, Mah J. Effects of surface conditioning on the shear bond strength of orthodontic brackets bonded to temporary polycarbonate crowns.. Am J Orthod Dentofacial Orthop. 2010; 138:72-78
Hammad SM, El Banna MS. Effects of cyclic loading on the shear bond strength of metal orthodontic brackets bonded to resin composite veneer surface using different conditioning protocols.. Prog Orthod. 2013; 14
Soon HI, Gill DS, Jones SP. A study to investigate the bond strengths of orthodontic brackets bonded to prosthetic acrylic teeth.. J Orthod. 2015; 42:192-199

An Overview of Orthodontic Bonding

From Volume 13, Issue 3, July 2020 | Pages 130-133

Authors

Robert S D Smyth

BDS, MClinDent, MFDS RCSEd, MOrth RCSEd, FHEA, Post-CCST

Articles by Robert S D Smyth

Abstract

Bonding brackets with composite resin is considered the gold standard in orthodontics. However, this can be challenging, especially where there is a requirement to bond to surfaces other than enamel, or where the enamel is defective. A choice of bonding modalities exists for these situations, and it is important that clinicians keep up-to-date with current techniques and practice. An overview of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic) is presented. Furthermore, a summary table providing a step-by-step guide for bonding techniques to various surfaces is provided.

CPD/Clinical Relevance: We provide an overview of the evidence and techniques available to the orthodontist for bonding brackets to enamel and other surfaces including: composite, porcelain, gold, amalgam and acrylic.

Article

Advancements in restorative dentistry over the last 50 years have meant that teeth previously considered of hopeless prognosis can now be restored and maintained. Despite the obvious advantages of tooth maintenance, this poses several challenges for the orthodontist, including the various surfaces to which brackets may need to be attached. This necessitates modifications to conventional bonding techniques.

This article provides an overview of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic). Furthermore, a summary table providing a step-by-step guide on bonding techniques for the various surfaces discussed is provided as an aide memoire.

Enamel

Direct bonding to enamel utilizes three principal agents: an enamel surface conditioner, a primer solution and an adhesive resin.

Surface conditioner

This creates micro-porosity and a high-energy enamel surface. Scanning electron micrographs are presented of normal enamel (Figure 1) and enamel that has been etched with 37% phosphoric acid for 15 seconds (Figure 2).

Figure 1. Scanning electron micrograph of normal enamel.
Figure 2. Scanning electron micrograph of enamel etched with 37% phosphoric acid for 15 seconds.

Primer

This flows into the etched surface to create resin tags so that, subsequently, a mechanical bond is created between the adhesive resin and the tooth surface.

Adhesive resin

This is the ‘cement’ which permits the bonding of materials to the tooth surface.

Buonocore originally introduced the enamel acid etch technique in 1955; he proposed conditioning with 85% phosphoric acid for 30 seconds.1 However, as research and practice evolved, it was found that 37% phosphoric acid utilized for 15 seconds was sufficient to develop a strong, durable bond to anterior teeth.2,3 For molars it has been suggested that an etching time of at least 30 seconds be utilized when bonding to the buccal surfaces of first molars, as it produces a more consistent bond strength compared to etching for 15 seconds.4

Self-etching primers (SEPs) provide a one stage alternative to conventional etching followed by primer application. Advantages of this approach include: ease of use, decreased technique sensitivity and a reduction in chairside time.5

The evidence comparing the relative benefits of SEPs and the acid etch technique is equivocal. A systematic review by Fleming et al concluded that there was weak evidence demonstrating higher odds of failure with SEPs over a 12-month period, but strong evidence for a time saving of approximately 8 minutes for full arch bonding.6 However, a more recent review concluded that there was no useable evidence to enable conclusions about failure rates for SEPs in comparison to acid etch and which is the most appropriate concentration or etching time.7

Although this present article focuses on the use of composite resin for bonding, it should be noted that glass ionomer cement (GIC) is an alternative adhesive. Glass ionomer cements can release fluoride and thus may prevent enamel decalcification8 whilst adhering to both enamel and metal.9 The bond strength is, however, weaker than composite resin and they have higher failure rates.10 There is some evidence that use of a GIC for bonding brackets may reduce the occurrence and severity of white spot lesions during orthodontic treatment,11 however, further high quality research is required.

In the absence of strong evidence in favour of either system, the choice of bonding modality remains at the discretion of the operator.

Bonding to defective enamel

It is not uncommon to encounter enamel surfaces that have developmental defects, such as those in amelogenesis imperfecta and molar incisor hypomineralization. Figures 3, 4 and 5 highlight the poor enamel formation in amelogenesis imperfecta, whilst Figures 6, 7 and 8 present a mild case of molar incisor hypomineralization. Clinical experience has shown that bond failure rates are higher in these cases; one reason for this may include the increased protein content of affected enamel. To address this, Venezie et al described the use of sodium hypochlorite to remove excess protein and improve the quality of etch in amelogenesis imperfecta cases.12 The evidence for improved bracket retention with these methods, however, remains weak and would not routinely be recommended.13 Whilst conventional etching is discouraged in these cases, as phosphoric acid may result in more enamel loss, SEPs may be used as an alternative because they produce a milder etch pattern and remove less enamel.14,15 Furthermore, the use of SEPs may help to reduce sensitivity that may be experienced by the patient during etching, rinsing and air-drying. Alternatively, the banding of molars may also be preferable.13

Figure 3. Amelogenesis imperfecta labial view.
Figure 4. Amelogenesis imperfecta upper occlusal view.
Figure 5. Amelogenesis imperfecta lower occlusal view.
Figure 6. Molar incisor hypomineralization labial view.
Figure 7. Molar incisor hypomineralization upper occlusal view.
Figure 8. Molar incisor hypomineralization lower occlusal view.

Bonding to composite labial veneers may result in increased bracket retention in cases affected by severe defects of enamel, as it is proposed that bonding to a larger area of composite resin increases bond strength when compared to bonding to the defective enamel alone.

Bonding to fluorosed enamel

For bonding to mildly fluorosed teeth, it has been reported that there is no significant difference in sheer bond strengths compared to that of normal enamel.16 An in vitro study by Isci et al, however, found that SEPs showed lower shear bond strength values for orthodontic brackets bonded to mildly fluorosed enamel.17

Composite resin

Bonding to composite resin requires superficial roughening, either through sandblasting with aluminium oxide or with diamond burs.18 Furthermore, an in vitro study concluded that a clinically acceptable bond strength can be achieved by surface conditioning of aged resin composite via the application of hydrofluoric acid, sandblasting with aluminium oxide, sodium bicarbonate particle abrasion, or a diamond bur.19 Subsequent bonding of brackets can be achieved by traditional orthodontic composites.

Porcelain

Bonding orthodontic brackets to porcelain/ceramic surfaces has a greater failure rate compared to enamel bonding.20 Therefore, several techniques have been suggested, which include:

Zachrisson and Büyükyilmaz :21

  • Deglaze porcelain − sandblasting with 50 μm aluminium oxide (2−4 seconds);
  • Etch − 9.6% hydrofluoric acid gel (2 minutes), rinse and dry;
  • Application of silane porcelain primer and air dry (2−3 coats);
  • Application of adhesive resin bonding agent.
  • Bourke and Rock:22

  • Etch − 37% phosphoric acid (60 seconds), rinse and dry;
  • Application of silane porcelain primer and air dry (3 coats);
  • Application of adhesive resin bonding agent.
  • Grewal Bach et al:20

  • Etch − 9.6% hydrofluoric acid (60 seconds) or mechanically roughened porcelain (sandblasting);
  • Rinse (30 seconds);
  • Air-dry;
  • Application of silane porcelain primer and lightly air-dry;
  • Application of adhesive resin bonding agent.
  • Hydrofluoric acid is highly corrosive, and should be used under rubber dam isolation and with high volume suction to prevent injury to the patient. Several primers are available for bonding to Zirconium crowns, for example, Assure®Plus (Reliance Orthodontic Products), All-Bond Universal® (Bisco, Schaumburg, Ill) and Scotchbond™ Universal (3M Unitek).23

    Gold

    Conventional acid etching is ineffective in the preparation of gold surfaces for mechanical retention of orthodontic attachments. Büyükyilmaz et al suggested that intra-oral sandblasting is utilized.24 This can be followed by bonding with a methacryloyloxyethyl trimellitate anhydride, (4-META) metal-bonding adhesive resin. Subsequent bonding of brackets can be achieved by traditional orthodontic composites. Research has shown that the bond strength achieved is comparable to that of acid-etched enamel.24

    Amalgam

    Successful bonding of orthodontic attachments to an amalgam surface requires conditioning of the amalgam (for example sandblasting), and use of a 4-META resin. Subsequent bonding of brackets to sandblasted and alloy primer-coated amalgam surfaces can be achieved by traditional primers and orthodontic composites.25

    An alternative is to use a hydrophilic primer containing biphenyl dimethacrylate, such as Assure® (Reliance Orthodontic Products). This allows for composite bonding to amalgam following sandblasting without the use of a separate metal primer.23 Subsequent bonding of brackets can be achieved by traditional orthodontic composites.

    Acrylic

    Acrylic teeth are often incorporated into orthodontic appliances as prosthetic teeth to mask spaces. Orthodontic brackets can be bonded to acrylic teeth using mechanical and chemical methods, or a combination of both. Mechanical retention includes sandblasting with aluminium oxide particles,26 the creation of undercut holes to facilitate a micro-mechanical ‘lock’ or roughening the surface with diamond or tungsten carbide burs.27 Chemical retention can be achieved using adhesive materials, such as cyanoacrylate.28

    Discussion

    Advancements in dentistry over the last 50 years have meant that teeth previously considered of hopeless prognosis can now be restored and maintained. Orthodontic clinicians must therefore possess the knowledge and skills to modify conventional bonding techniques, which are summarized in Table 1. A summary table (Table 2) has been developed as an aide memoire for required alterations to the enamel bonding process that allow for orthodontic brackets to be bonded to composite, porcelain, zirconia, metal and acrylic.


    Etch and Rinse SEP
  • Thorough prophylaxis − Rinse & Dry
  • Isolate the teeth for etching. With a microbrush, dab the etching agent (phosphoric acid) onto area to be bonded
  • Allow 15−30 seconds for etching
  • Rinse & Dry for 10 seconds
  • The etched area should appear frosty white. If not, re-etch for an additional 20 seconds
  • Apply 1 coat of hydrophilic primer resin and lightly dry with air
  • Proceed with the application of adhesive resin and bracket
  • Light cure 10−20 seconds
  • Thorough prophylaxis − Rinse & Dry
  • Using a microbrush, apply a small amount of mixed solution to the enamel and scrub for 5 seconds where the bracket will be applied
  • Dry the enamel surface with 2 bursts of compressed air
  • Proceed with the application of adhesive resin and bracket
  • Light cure 10−20 seconds

  • Bonding to a Composite Surface Bonding to a Porcelain Surface Bonding to a Zirconia Surface Bonding to a Metal Surface (Gold, Amalgam, Stainless Steel) Bonding to an Acrylic Surface
  • Thorough prophylaxis − Rinse & Dry
  • Roughen the composite surface with a fine diamond bur − Rinse & Dry
  • If there is enamel present – Etch, Rinse & Dry
  • Apply 1 coat of hydrophilic primer resin and lightly dry with air
  • Proceed with the application of adhesive resin and bracket
  • Light cure for double time
  • Thorough prophylaxis − Rinse & Dry
  • Sandblast porcelain surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry OR Isolate tooth, etch with 9.6% hydrofluoric acid for 1 minute, Rinse 30 seconds & Dry
  • Apply 1 thin layer of silane coupling agent − lightly dry with air
  • Apply 1 coat of hydrophilic primer resin & air dry
  • Proceed with application of adhesive resin and bracket
  • Light cure for double time
  • Sandblast metal surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry OR Isolate tooth, etch with 9.6% hydrofluoric acid for 1 minute, Rinse 30 seconds & Dry Apply 1 thin layer of silane coupling agent − lightly dry with air
  • Apply 1 coat of hydrophilic primer resin & air dry
  • Light cure resin for 10 seconds
  • Proceed with application of adhesive resin and bracket
  • Light cure for double time
  • Thorough prophylaxis − Rinse & Dry
  • Sandblast metal surface with 50 μm aluminium oxide for 2−4 secs − Rinse & Dry. If no enamel present proceed to Step 4.
  • If there is enamel present – Etch, Rinse & Dry
  • Apply 1 coat of hydrophilic primer resin & air dry
  • Proceed with application of adhesive resin and bracket
  • Light cure for double time
  • Roughen the acrylic surface with a fine diamond bur − Rinse & Dry
  • Apply one coat of hydrophilic primer resin and lightly dry with air
  • Proceed with the application of adhesive resin and bracket
  • Light cure for double time
  • This article has provided an overview of some of the evidence and techniques available for bonding to enamel and other surfaces (composite, porcelain, gold, amalgam and acrylic). Despite all efforts to improve bond strength in compromising situations, repeated bond failures may still occur. In these situations, it may be necessary to resort to banding teeth and accepting the associated disadvantages.

    Conclusion

  • There is weak evidence indicating a higher odds of failure with SEPs than etch and rinse over 12 months in orthodontic patients;
  • In the absence of clear evidence to favour either system, the choice of bonding modality remains at the discretion of each operator;
  • A convenient table is presented to act as an aide memoire for readers highlighting techniques for bonding to enamel and the various restorative materials encountered in adolescent and adult orthodontic patients.